Introduction to Coordination Complexes for NEET
Coordination complexes, also known as coordination compounds, are an essential topic in NEET Chemistry. Questions from this chapter frequently appear in competitive exams like NEET. Understanding the concepts and solving multiple-choice questions (MCQs) is the best way to strengthen your grasp of this topic.
In this article, we provide a comprehensive set of Coordination Complex MCQs for NEET, along with answers and explanations. These questions are carefully curated from NEET World to help students ace their exams.
Important Concepts of Coordination Complexes
Definition of Coordination Compounds
Coordination compounds consist of a central metal atom or ion bonded to a group of molecules or ions called ligands. The metal and ligands together form a complex ion, which can be neutral, cationic, or anionic.
Types of Ligands
Ligands are classified based on their donor atoms and number of donor sites:
- Monodentate ligands – Bind through one donor atom (e.g., Cl⁻, NH₃).
- Bidentate ligands – Bind through two donor atoms (e.g., ethylenediamine).
- Polydentate ligands – Bind through multiple donor atoms (e.g., EDTA).
Coordination Number and Geometry
The coordination number is the number of ligands attached to the central metal ion. Common geometries include:
- 2 – Linear
- 4 – Tetrahedral or Square Planar
- 6 – Octahedral
Isomerism in Coordination Compounds
Coordination compounds exhibit structural and stereoisomerism, including:
- Geometrical isomerism (e.g., cis-trans isomerism in square planar and octahedral complexes).
- Optical isomerism (complexes that rotate plane-polarized light).
Bonding Theories
- Valence Bond Theory (VBT) explains the hybridization of metal orbitals.
- Crystal Field Theory (CFT) explains ligand-induced splitting of d-orbitals.
- Molecular Orbital Theory (MOT) describes bonding through molecular orbitals.
Coordination Complex MCQs for NEET Exam – Topic-wise Questions
MCQs on Basic Concepts
- Which of the following is a coordination compound?
a) NaCl
b) K₄[Fe(CN)₆]
c) H₂O
d) CO₂
Answer: b) K₄[Fe(CN)₆] - The coordination number of Pt in [Pt(NH₃)₂Cl₂] is:
a) 2
b) 4
c) 6
d) 3
Answer: b) 4 - The ligand in [Cu(NH₃)₄]²⁺ is:
a) Cu²⁺
b) NH₃
c) H₂O
d) Cl⁻
Answer: b) NH₃
MCQs on Coordination Number and Geometry
- The shape of [Ni(CN)₄]²⁻ is:
a) Tetrahedral
b) Square planar
c) Octahedral
d) Trigonal planar
Answer: b) Square planar - The hybridization of the central metal in [Fe(CN)₆]³⁻ is:
a) sp³
b) sp³d²
c) d²sp³
d) sp²
Answer: c) d²sp³
MCQs on Isomerism
- Which of the following complexes shows geometrical isomerism?
a) [Co(NH₃)₆]³⁺
b) [CoCl₂(NH₃)₄]⁺
c) [Cu(NH₃)₄]²⁺
d) [Fe(CN)₆]³⁻
Answer: b) [CoCl₂(NH₃)₄]⁺ - Optical isomerism is exhibited by:
a) [PtCl₂(NH₃)₂]
b) [Co(en)₃]³⁺
c) [NiCl₄]²⁻
d) [Ag(NH₃)₂]⁺
Answer: b) [Co(en)₃]³⁺
MCQs on Bonding Theories
- In crystal field theory, strong field ligands cause:
a) High spin complexes
b) Low spin complexes
c) No effect on spin
d) Increase in coordination number
Answer: b) Low spin complexes - The splitting pattern of d-orbitals in an octahedral field is:
a) t₂g lower, eg higher
b) eg lower, t₂g higher
c) All orbitals degenerate
d) No splitting occurs
Answer: a) t₂g lower, eg higher
MCQs on Applications and Importance
- Which of the following is used in cancer treatment?
a) [Fe(CN)₆]³⁻
b) [PtCl₂(NH₃)₂] (Cisplatin)
c) [Cu(NH₃)₄]²⁺
d) [Ag(NH₃)₂]⁺
Answer: b) [PtCl₂(NH₃)₂] (Cisplatin)
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Answers and Explanations for MCQs
Each question is designed to test your understanding of coordination complexes. Detailed explanations of all answers can be found in NEET World’s study materials.
Conclusion
Coordination compounds are a vital topic in NEET Chemistry. Understanding key concepts and practicing MCQs can significantly boost your performance. Stay consistent, solve more questions, and keep revising!
FAQs on Coordination Complexes for NEET
- Why are coordination complexes important for NEET?
- They frequently appear in the exam and help understand bonding theories.
- How can I memorize ligand names easily?
- Use mnemonics and revise regularly.
- Which book is best for NEET coordination compounds?
- NCERT Chemistry and NEET World materials.
- What is the best way to solve MCQs quickly?
- Understand concepts rather than memorize answers.
- Are coordination compounds difficult for NEET?
- No, with proper practice, they become easy to master.